Friday 23 March 2018

Section 1 g) Specification

1.38 describe the formation of a covalent bond by the sharing of a pair of
electrons between two atoms

A covalent bond is formed between two non-metals and involves the atoms sharing one or more pairs of electrons


1.39 understand covalent bonding as a strong attraction between the bonding
pair of electrons and the nuclei of the atoms involved in the bond

In a covalent bond, the nucleus of each atom is attracted to the other atom's outer shell electron(s).

1.40 explain, using dot and cross diagrams, the formation of covalent compounds
by electron sharing for the following substances:
i hydrogen
ii chlorine
iii hydrogen chloride
iv water
v methane
vi ammonia
vii oxygen
viii nitrogen
ix carbon dioxide
x ethane
xi ethene













1.41 understand that substances with simple molecular structures are gases or
liquids, or solids with low melting points

Simple covalent compounds have strong bonds, but very weak intermolecular forces. These don't require much energy to break, leading to low melting and boiling points. As a result, most simple covalent compounds are gas or liquid at room temperature.

1.42 explain why substances with simple molecular structures have low melting
and boiling points in terms of the relatively weak forces between the
molecules

There aren't very strong forces of attraction between covalent molecules, they have weak intermolecular forces that are easily broken; they don't require much energy to break. This means that they have low melting and boiling points.

1.43 explain the high melting and boiling points of substances with giant covalent
structures in terms of the breaking of many strong covalent bonds

In giant covalent structures, each atom is bonded to another with by strong covalent bonds. These are not easily broken, they require a lot of energy to break. Additionally, in a giant structure there are so many bonds to break that it requires even more. This results in very high melting and boiling points.

1.44 draw diagrams representing the positions of the atoms in diamond
and graphite



1.45 explain how the uses of diamond and graphite depend on their
structures, limited to graphite as a lubricant and diamond in cutting.

In diamond, the carbon atoms are arranged in a tetrahedronal structure, each atom with four strong covalent bonds. This makes it very hard, with a very high melting and boiling point. It has lots of very strong bonds. Its giant structure means that it forms in crystals that reflect light and let it pass through. It is so hard that its use in industrial saws etc. is ideal, it can cut through almost anything.

Graphite is arranged in layers held together by weak intermolecular forces. This means that when force is applied, the layers slide over each other easily, making graphite a good lubricant.

Both diamond and graphite are allotropes of carbon, but buckminsterfullerene is another one, it's ball shaped, made of 60 carbon atoms, and used for lubrication, drug administration, and in catalysts. 

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Section 3 a) Specification

3.1 explain the terms homologous series, hydrocarbon, saturated, unsaturated, general formula and isomerism. A homologous series is a grou...