Showing posts with label f) Ionic compounds. Show all posts
Showing posts with label f) Ionic compounds. Show all posts

Friday, 23 March 2018

Section 1 f) Summary

Ionic compounds are formed when a metal and non-metal meet, and there is a transfer of electrons. This causes both atoms to become oppositely charged ions, which experience strong forces of electrostatic attraction towards each other.


Ionic compounds are not easily broken apart, their strong forces of attraction mean they have high melting and boiling points: they require a lot of energy to break the bonds.
The compounds, as a solid, form a giant ionic lattice structure. It is a lattice, meaning it is regular which results in the solids forming into translucent, geometric crystals (think of salt).

This can be represented at a molecular level using the following diagram:
The positive and negative ions alternate, because like attractions repel and opposites attract. Therefore, when force is applied to an ionic solid, it breaks easily: it is brittle. This is because when the ions are forced to move, they don't slide over each other easily, they get close to a similar charge, causing a force of repulsion and making it break apart easily.

It is important to know the charges of ions seen commonly in this topic. We can deduce the charge based on the number of outer shell (valence) electrons (if it has two, it will lose them, if it has six, it will gain two, etc.)
The following periodic table is a useful guide on the trends:


Section 1 f) Key Words

Anion: Negatively charged ion

Cation: Positively charged ion

Ion: Charged particle, atom with extra electron/s or missing electron/s

Oxidation: Loss of electrons

Reduction: Gain of electrons

Section 1 f) Specification

1.28 describe the formation of ions by the gain or loss of electrons

An ion is formed when an atom loses an electron (It is reduced) or gains an electron (it is oxidised). This change in electron number means the atom has gained a charge. If it has been oxidised, it will become a negative ion: an anion. If it has been reduced, it will become a positive ion: a cation. In ionic bonding, one or more electrons is transferred from one atom to another, turning both into oppositely charged ions which are strongly attracted to one another.

1.29 understand oxidation as the loss of electrons and reduction as the gain of
electrons

OILRIG:
Oxidation
Is
Loss of electrons
Reduction
Is
Gain of electrons

1.30 recall the charges of common ions in this specification

Lithium: Li+
Chlorine: Cl-
Fluorine: F-
Hydrogen: H+
Potassium: K+
Magnesium: Mg2+
Oxygen: O2-

General rule: non-metals are negative, metals are positive



1.31 deduce the charge of an ion from the electronic configuration of the atom
from which the ion is formed

You can look at the outer shell of an atom to determine its ionic charge. If the atom has 2 outer shell electrons, it will lose them and have a charge of 2+. If it has 5 outer shell electrons, it will gain 3, leaving it with a charge of 3-.

1.32 explain, using dot and cross diagrams, the formation of ionic compounds by
electron transfer, limited to combinations of elements from Groups 1, 2, 3
and 5, 6, 7

Ionic bonding is between a metal and a non-metal, the outer shell electrons transferring from the metal to the non metal to give both a full outer shell.

1.33 understand ionic bonding as a strong electrostatic attraction between
oppositely charged ions

The ions become oppositely charged when the electrons are transferred. They experience strong forces of attraction, because opposite charges attract. This forms a strong ionic bond.

1.34 understand that ionic compounds have high melting and boiling points
because of strong electrostatic forces between oppositely charged ions

After transferring electrons, atoms become charged ions which experience strong attraction to opposite charges. This means the electrons are bound by strong electrostatic forces of attraction in this structure:
The strong forces of attraction require a lot of energy to be broken, which is why they have a high melting and boiling point.

1.35 understand the relationship between ionic charge and the melting
point and boiling point of an ionic compound

The bigger the charge, the higher the melting and boiling point as higher charge means stronger forces of attraction.

1.36 describe an ionic crystal as a giant three-dimensional lattice
structure held together by the attraction between oppositely
charged ions

Ionic crystals are held together by the strong forces of attraction between the positively and negatively charged ions. This forms a giant structure, meaning it repeats over and over, and it is a three-dimensional lattice, meaning it is a regular structure that has gaps etc. that allow light to pass through; this is why salt crystals are translucent.

1.37 draw a diagram to represent the positions of the ions in a crystal of
sodium chloride.

Green: Chlorine
White/Grey: Sodium

Section 3 a) Specification

3.1 explain the terms homologous series, hydrocarbon, saturated, unsaturated, general formula and isomerism. A homologous series is a grou...